Breakthrough in nanotechnology by uncovering conductive property of carbon-based molecules

Newfound ability of organic molecules to conduct electricity opens door to smaller, cheaper and more powerful technologies

PITTSBURGH—University of Pittsburgh researchers have discovered that certain organic—or carbon-based—molecules exhibit the properties of atoms under certain circumstances and, in turn, conduct electricity as well as metal. Detailed in the April 18 edition of Science, the finding is a breakthrough in developing nanotechnology that provides a new strategy for designing electronic materials, including inexpensive and multifunctional organic conductors that have long been considered the key to smaller, cheaper, and faster technologies.

The Pitt team found that the hollow, soccer-ball-shaped carbon molecules known as fullerenes can hold and transfer an electrical charge much like the most highly conductive atoms, explained project head Hrvoje Petek, a professor of physics and chemistry in Pitt’s School of Arts and Sciences and codirector of Pitt’s Petersen Institute for NanoScience and Engineering. The research was performed by Pitt post-doctoral associates Min Feng and Jin Zhao.

When an electron was introduced into a fullerene molecule, the shape of the electron distribution mimicked that of a hydrogen atom or an atom from the alkali metal group, which includes lithium, sodium, and potassium. Moreover, when two fullerenes were placed next to each other on a copper surface, they showed the electron distribution of their chemical bond and appeared as H2, a hydrogen molecule. The assembly exhibited metal-like conductivity when the team extended it to a wire 1-molecule-wide.